Helium and carbon isotopes in fluorites: implications for mantle carbon contribution in an ancient subduction zone   总被引：1，自引：0，他引：1  

Junji Yamamoto  Makoto Watanabe  Yoshiyuki Nozaki  Yuji Sano   《Journal of Volcanology and Geothermal Research》2001,107(1-3)

The concentrations of helium and carbon in fluorite associated with Cretaceous to Neogene (90–13 Ma) granitic magmatism in the Japanese arc have been measured. Concentrations of Li, U, Th and Gd were measured to correct for secondary generated ³He. The CO₂/³He of fluorites are almost uniform (1.5×10¹⁰–4×10¹⁰) and in fair agreement with the range of present island arc volcanic gases. The calculated mantle C contribution in the Mesozoic subduction zone appear to have been identical to the present one (7–19%) indicating that the C flux from the mantle in supra-subduction zone environments has remained fairly constant during the past 70 million years.  相似文献   

Crystallization of chondrules in ordinary chondrites     

Makoto Kimura  Kenzo Yagi 《Geochimica et cosmochimica acta》1980,44(4):589-602

The process of crystallization and the origin of chondrules are discussed, in terms of the phase relations of the minerals in chondrules in six ordinary chondrites of the Yamato-74 meteorites, especially the Yamato-74191 (L3).Chondrules are classified into six types. The bulk compositions of chondrules projected onto the MgO-FeO-SiO₂ system show that the compositions of chondrules vary widely. Investigations by means of the MgO-Al₂O₃-SiO₂ system indicate that porphyritic chondrules can be regarded as products of supercooling crystallization. The growth rates of crystals in porphyritic chondrules were fairly small. The difference between types of chondrules is interpreted in terms of the compositions of chondrules and the nucleation temperatures of the supercooled droplets.All these observations and estimations must be taken into account for discussing the origin of chondrules. The impact and dust fusion theories do not appear to be plausible. Molten droplets due to these mechanisms will be glassy spherules, or crystallize at equilibrium. Only a liquid condensation theory can well explain the characteristic features and the process of the crystallization of chondrules.  相似文献   

A high pressure experimental study on a magnesian-rich leucite-lamproite from the West Kimberley area,Australia: petrogenetic implications     

Makoto Arima  Alan D. Edgar 《Contributions to Mineralogy and Petrology》1983,84(2-3):228-234

Liquidus and subliquidus phase relations of a leucite-lamproite (wolgidite) from the West Kimberley area, Australia have been studied experimentally under the volatile conditions of 3.22 wt.% H₂O ( \(X_{CO_2 }\) =0.11) and 13.0 wt.% H₂O ( \(X_{CO_2 }\) =0.03) between 10 to 40 kbar. Under these conditions, liquids are vapour undersaturated. In experiments with 13.0 wt.% H₂O, olivine is the liquidus phase up to 24 kbar and orthopyroxene above 24 kbar. Phlogopite and rutile occur close to the liquidus above 16 kbar. Crystallization temperatures of clinopyroxenes are 50–120° C below the liquidus. Based on these results, wolgidite magma is unlikely to be a partial melt of a garnet- or spinel-lherzolite mantle but could be derived from phlogopite+rutile±olivine±or-thopyroxene assemblages occurring as metasomatized mantle.  相似文献   

P-T Conditions of Metamorphism in the Neoproterozoic Rocks of the Negele Area, Southern Ethiopia     

Tadesse Yihunie  Mamoru Adachi  Makoto Takeuchi 《Gondwana Research》2004,7(2):489-500

Neoproterozoic rocks constitute the Kenticha, Alghe and Bulbul litho-tectonic domains in the Negele area of southern Ethiopia. Structural features and fabrics in these rocks were developed during north-south folding (D1), thrusting (D2) and shearing (D3) deformation. From micro-structural inferences and fabric relationships in semi-pelitic schists/gneisses of the Kenticha and Alghe domains, three episodes of metamorphic mineral growths (M1, M2 and M3) are inferred to have accompanied the deformational events. Pressure-Temperature estimates on equilibrium garnet-plagioclase-biotite and garnet-biotite assemblages from semi-pelitic schists/gneisses of the two domains indicate metamorphic recrystallization at temperatures of 520–580°C and 590–640°C, and pressures of 4–5 kb and 6–7 kb in the Kenticha and Alghe domains, respectively. These results correspond to regional metamorphism at a depth of 16–20 km for the Kenticha and 22–25 km for the Alghe domains. The P-T results suggest that the protoliths to the rocks of the Kenticha and Alghe domains were subjected to metamorphism at different crustal depths. This implies exhumation of the Alghe gneissic rocks from intermediate crustal level (ca. 25 km) before juxtaposition with the Kenticha sequence along a north-south trending thrust at the present crustal level during the Neoproterozoic. The combined deformation, fabric and mineral growth data suggest that rocks in the Kenticha and Alghe domains evolved under similar tectono-metamorphic conditions, which resulted from crustal thickening and uplift followed by extension and orogenic collapse, exhumation and cooling before litho-tectonic domains coalesced and cratonized in the Neoproterozoic southern Ethiopian segment of the East African Orogen.  相似文献   

Thermally controlled processes and preserved thermal signatures within the Earth     

Makoto Taniguchi  Ilmo T. Kukkonen 《Physics of the Earth and Planetary Interiors》2005,152(4):221-222

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The Behavior of Ni(II), Cr(III), and Zn(II) in Biological Wastewater Treatment Process     

Soon‐An Ong  Eiichi Toorisaka  Makoto Hirata  Tadashi Hano 《洁净——土壤、空气、水》2005,33(2):95-103

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Chemical and isotopic signatures of the basement rocks from the Campi Flegrei geothermal field (Naples, southern Italy): inferences about the origin and evolution of its hydrothermal fluids     

Graziella Caprarelli  Makoto Tsutsumi  Bruno Turi 《Journal of Volcanology and Geothermal Research》1997,76(1-2)

The Campi Flegrei (Naples, Campanian Plain, southern Italy) geothermal system is hosted by Quaternary volcanic rocks erupted before, during and after the formation of the caldera that represents one of the major structural features in the Neapolitan area. The volcanic products rest on a Mesozoic carbonate basement, cropping out north, east and south of the area. Chemical (major, minor and trace elements) and stable isotope (C, H, O) analyses were conducted on drill-core samples recovered from geothermal wells MF-1, MF-5, SV-1 and SV-3, at depths of ˜ 1100 to 2900 m. The study was complemented by petrographic and SEM examination of thin sections. The water which feeds the system is both marine and meteoric in origin. Mineral zonation typical of a high-temperature geothermal system exists in all the geothermal wells; measured temperatures in wells are as high as ˜ 400 °C. The chemical composition of the waters suggests the existence of two reservoirs: a shallow reservoir (depth < 2000 m) fed by seawater that boiled at 320 °C and became progressively diluted by steam-heated local meteoric water during its ascent; and a deeper reservoir (depth > 2000 m) of hypersaline water. The drill-cores are mainly hydrothermally altered volcanics of trachy-latitic affinity, but some altered pelites and limestones are also present. Published Na, Mg and K concentrations of selected geothermal waters indicate that the hydrothermal fluids are in equilibrium with their host rocks, with respect to K-feldspar, albite, sericite and chlorite. The measured δ¹⁸O_(SMOW) values of rocks range from +4.3 to + 16.5%. The measured δD_(SMOW) values range from − 79 to − 46%. The calculated isotopic composition of the fluids at equilibrium with the samples vary from + 1 to + 8.3%. δ¹⁸O and from − 52 to + 1%. δD. The estimated isotopic composition of the waters at equilibrium with the studied samples confirmed the existence of two distinct fluid types circulating in the geothermal system. The shallower has a marine water signature, while the deeper water has a signature consistent both with magmatic and meteoric origins. In the latter case, the recharge of this aquifer likely occurs at the outcrop of the Mesozoic Limestones surrounding the Campanian Plain; after infiltration, the water percolates through evaporitic layers, becoming hypersaline and D-depleted.  相似文献   

Jurassic kimberlites from Picton and Varty Lake,Ontario: Geochemical and stable isotopic characteristics     

Makoto Arima  Robert Kerrien 《Contributions to Mineralogy and Petrology》1988,99(3):385-391

Micaceous ultramafic dikes of Jurassic age from Picton and Varty Lake, Ontario, consist mineralogically of olivine — phlogopite — serpentine — calcite-spinel. The rocks are characterized by abundant Ba-rich phlogopite (up to 6.5 wt.% BaO) and spinels with a diagnostic kimberlite trend-1. Compositionally the dikes are characterized by extreme silica-undersaturation (21–30 wt.% SiO₂), primitive Mg/(Mg + Fe^T) ratios (0.75–0.83), large enrichments of volatile components (CO₂ and H₂O), and relatively high abundances of both incompatible and compatible trace elements. The dikes exhibit pronounced enrichments of light rare earth elements (LREE) (La_N=320–1330) combined with strongly fractionated patterns (La_N/Yb_N=45–108). Calcite in the dikes is a primary magmatic phase, from textural relations and C-isotopic compositions ( ¹³C= –4.0 to –8.3). A calcite-rich aphanitic phase of the Picton dike is interpreted to be a late stage magmatic differentiate, which possibly involved olivine fractionation. Although the dikes lack most of the macrocrysts generally considered to be important diagnostic minerals of kimberlite magmatism, the geochemical, mineralogical and C- and O-isotopic characteristics collectively indicate that the dikes are evolved varieties of hypabyssal facies kimerlite.  相似文献   

Effect of the contraction of Zn-O bonds on X-ray emission spectra     

Kimura  Makoto  Ohashi  Haruo  Osawa  Toshikazu 《Physics and Chemistry of Minerals》1988,15(6):545-547

Physics and Chemistry of Minerals - The X-ray emission spectra were measured for tetrahedrally coordinated Zn ion in several synthetic compounds. Intensity ratios of L β and L α spectral...  相似文献   

Magnetic and electric field observations during the 2000 activity of Miyake-jima volcano, Central Japan   总被引：1，自引：0，他引：1  

Yoichi Sasai  Makoto UyeshimaJacques Zlotnicki  Hisashi UtadaTsuneomi Kagiyama  Takeshi HashimotoYuji Takahashi 《Earth and Planetary Science Letters》2002,203(2):769-777

Magnetic and electric field variations associated with the 2000 eruption of Miyake-jima volcano are summarized. For about 1 week prior to the July 8 phreatic explosion, significant changes in the total intensity were observed at a few stations, which indicated uprising of a demagnetized area from a depth of 2 km towards the summit: this non-magnetic source can be regarded as a vacant space itself. Electric and magnetic field variations were observed simultaneously associated with the tilt-step event, which was the abrupt (∼50 s) inflation at a few km depth within the volcano followed by gradual recovery (∼several hours). The electric field is ascribed to the electrokinetic effect most probably due to forced injection of fluids from the source, while the magnetic field to the piezomagnetic effect due to increased pressure. Large magnetic variations amounting to a few tens of nT were observed at several stations since July 8, and they turned almost flat after the August 18 largest eruption. Magnetic changes are explained mostly by the vanishing of magnetic mass in the summit and additionally by the thermal demagnetization at a rather shallow depth. A large increase in the self-potential by 130 mV was also observed near the summit caldera associated with the August 18 eruption, which suggests that the hydrothermal circulation system sustained within the volcano for the past more than 10 years was destroyed by this eruption.  相似文献